Catecholate LMCT bands as probes for the active sites of nonheme iron oxygenases

…, SJ Benkovic, LM Bloom, FC Bradley…

Index: Cox, D. D.; Benkovic, S. J.; Bloom, L. M.; Bradley, F. C.; Nelson, M. J.; et al. Journal of the American Chemical Society, 1988 , vol. 110, # 7 p. 2026 - 2032

Full Text: HTML

Citation Number: 202

Abstract

Conclusions The results of this study show that state-of-the-art'H CRAMPS NMR techniques, including various kinds of relaxation experiments, are capable not only of distinguishing structurally different types of hydroxyl moieties on a silica surface but also of addressing the issue of proximity of one type relative to the others. Two distinctly different types of silanol groups are identified, and it is found that the hydrogen-bonded types are the ones that are ...

Related Articles:

Synthesis and initial in vitro biological evaluation of two new zinc-chelating compounds: comparison with TPEN and PAC-1

[Astrand, O. Alexander H.; Aziz, Gulzeb; Ali, Sidra Farzand; Paulsen, Ragnhild E.; Hansen, Trond Vidar; Rongved, Pal Bioorganic and Medicinal Chemistry, 2013 , vol. 21, # 17 p. 5175 - 5181]

Coordination modes of bridge carboxylates in dinuclear manganese compounds determine their catalase-like activities

[Jiang, Xiaojun; Liu, Hui; Zheng, Bing; Zhang, Jingyan Dalton Transactions, 2009 , # 40 p. 8714 - 8723]

More Articles...