Organometallics

Reversible insertion reactions of a platinum germylene complex

KE Litz, K Henderson, RW Gourley, MMB Holl

Index: Litz, Kyle E.; Henderson, Kenneth; Gourley, Randall W.; Holl, Mark M. Banaszak Organometallics, 1995 , vol. 14, p. 5008 - 5010

Full Text: HTML

Citation Number: 53

Abstract

Summary: Dihydrogen and carbon dioxide react reversibly with the three-coordinate complex (Et3P) zPtGe-[N (SiMed&. These reactions demonstrate the ability of germylenes to act as strong supporting ligands, while introducing new modes of reactivity via formal Ge (II) I