Synthesis, structure, and catalytic activity of novel trinuclear rare-earth metal amido complexes incorporating μ–η 5: η 1 bonding indolyl and μ 3-oxo groups

…, S Wang, Z Feng, Y Wei, H Miao, L Guo, F Wang…

Index: Yang, Song; Zhu, Xiancui; Zhou, Shuangliu; Wang, Shaowu; Feng, Zhijun; Wei, Yun; Miao, Hui; Guo, Liping; Wang, Fenhua; Zhang, Guangchao; Gu, Xiaoxia; Mu, Xiaolong Dalton Transactions, 2014 , vol. 43, # 6 p. 2521 - 2533

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Citation Number: 13

Abstract

The reactions of different pyrrolyl-functionalized indoles with rare-earth metal (III) amides [(Me3Si) 2N] 3REIII (μ-Cl) Li (THF) 3 (RE= Yb, Er, Dy, Eu, Y) produced different kinds of rare- earth metal amido complexes. Reactions of N-((1H-pyrrol-2-yl) methylene)-2-(1H-indol-3-yl) ethanamine with rare-earth metal amides [(Me3Si) 2N] 3REIII (μ-Cl) Li (THF) 3 (RE= Yb, Er, Dy, Eu, Y) in toluene or THF at temperatures of 75–80° C afforded the novel trinuclear rare ...

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