Stereoisomeric 1, 2, 4, 6, 7, 9-hexaoxecan derivatives from dimerisation of a 1, 2, 4-trioxolan; stereospecific interconversion

G Rio, MJ Rio

Index: Rio, Guy; Rio, Marie-Jeanne Journal of the Chemical Society, Chemical Communications, 1982 , # 1 p. 72 - 74

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Abstract

Carbon disulphide and other acceptors catalyse the dimerisation of the endoperoxide formed from photo-oxygenation of 1, 3-diphenylisobenzofuran to mixtures of four stereoisomeric diperoxides; pairs of these dimers are stereospecifically interconvertible on gentle heating.

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