Heterocycles

Synthesis of Annulated 1, 4-Dioxanes and Perhydro 1, 4-oxazines by Domino-Wacker-Carbonylation and Domino-Wacker-Mizoroki-Heck Reactions

LF Tietze, A Heins, M Soleiman-Beigi, C Raith

Index: Tietze, Lutz F.; Heins, Arne; Soleiman-Beigi, Mohammad; Raith, Christian Heterocycles, 2009 , vol. 77, # 2 p. 1123 - 1146

Full Text: HTML

Citation Number: 10

Abstract

Abstract–Palladium (II)-catalyzed domino reactions for the formation of 1, 4-dioxanes and perhydro-1, 4-oxazines starting from hydroxy alkenes are described. The domino-Wacker- carbonylation comprises a Wacker oxidation, subsequent CO-insertion and a nucleophilic substitution of the intermediately formed Pd-species. The domino-Wacker-Mizoroki-Heck reaction proceeds via a Wacker oxidation, subsequent insertion into the olefinic π-bond of ...

Related Articles:

Kinetic resolution of trans-cycloalkane-1, 2-diols via Steglich esterification

[Hrdina, Radim; Mueller, Christian E.; Schreiner, Peter R. Chemical Communications, 2010 , vol. 46, # 15 p. 2689 - 2690]

Enantioselective catalytic ring opening of epoxides with carboxylic acids

[Jacobsen, Eric N.; Kakiuchi, Fumitoshi; Konsler, Reed G.; Larrow, Jay F.; Tokunaga, Makoto Tetrahedron Letters, 1997 , vol. 38, # 5 p. 773 - 776]

Synthesis of highly modular bis (oxazoline) ligands by Suzuki cross-coupling and evaluation as catalytic ligands

[Cattoen, Xavier; Pericas, Miquel A. Tetrahedron, 2009 , vol. 65, # 39 p. 8199 - 8205]

Lipophilic oligopeptides for chemo-and enantioselective acyl transfer reactions onto alcohols

[Mueller, Christian E.; Zell, Daniela; Hrdina, Radim; Wende, Raffael C.; Wanka, Lukas; Schuler, Soeren M. M.; Schreiner, Peter R. Journal of Organic Chemistry, 2013 , vol. 78, # 17 p. 8465 - 8484]

Resolution of Diols via Catalytic Asymmetric Acetalization

[Hofmann, Christine; Schuler, Soeren M. M.; Wende, Raffael C.; Schreiner, Peter R. Chemical Communications, 2014 , vol. 50, # 10 p. 1221 - 1223]

More Articles...