On the enantioselectivity of aziridination of styrene catalysed by copper triflate and copper-exchanged zeolite Y: consequences of the phase behaviour of …

…, D Arquier, B Kariuki, D Bethell, PCB Page…

Index: Jeffs, Laura; Arquier, Damien; Kariuki, Benson; Bethell, Donald; Page, Philip C. Bulman; Hutchings, Graham J. Organic and Biomolecular Chemistry, 2011 , vol. 9, # 4 p. 1079 - 1084

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Citation Number: 9

Abstract

By synthesising S-2-phenyl-N-(4-nitrophenyl) aziridine from S-phenylglycinol, it has been demonstrated that the aziridination of styrene by [N-(4-nitrobenzenesulfonyl) imino] phenyliodinane (nosyliminophenyliodinane, PhINNs) in the presence of S, S-2, 2′- isopropylidene-bis (4-phenyl-2-oxazoline), catalysed by copper (II) triflate in CH3CN solution or heterogeneously by CuHY, has predominantly an R-configuration. The ...

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