The Journal of Organic Chemistry

Reactions of. alpha.-chloro epoxides. 1. Hydrolysis of 1, 3-dichloropropene oxide

B Gold, T Leuschen

Index: Gold, Barry; Leuschen, Thomas Journal of Organic Chemistry, 1981 , vol. 46, # 7 p. 1372 - 1373

Full Text: HTML

Citation Number: 7

Abstract

In a recent paper Kline, Solomon, and Van Duuren studied the hydrolysis and thermolysis of several a-chloro epoxides, including cis-and trans-1, 3-dichloropropene oxide (la and lb, respectively). l They reported that both la and lb afford a-chloroacrylaldehyde (2) upon hydrolysis in pH 7.4 buffer at 37" C with pseudo-first-order rate constants (kH) determined to be 2.4 X min-', respectively. They also indicated that thermolysis of lb at 200" C in xylene ...

Related Articles:

Enantioselective Diels–Alder reactions with anomalous endo/exo selectivities using conformationally flexible chiral supramolecular catalysts

[Hatano, Manabu; Mizuno, Tomokazu; Izumiseki, Atsuto; Usami, Ryota; Asai, Takafumi; Akakura, Matsujiro; Ishihara, Kazuaki Angewandte Chemie - International Edition, 2011 , vol. 50, # 51 p. 12189 - 12192]

STUDIES OF CONJUGATED SYSTEMS. V. THE PREPARATION AND CHLORINATION OF BUTADIENE

[Muskat; Northrup Journal of the American Chemical Society, 1930 , vol. 52, p. 4054]

BIBLIOGRAPHIE D'HISTOIRE DE L'ÉDUCATION FRANÇAISE: Titres parus au cours de l'année 1977 et suppléments de l'année 1976

[Moureu; Robin Annales de Chimie (Cachan, France), 1921 , vol. <9>15, p. 209]

More Articles...