The Journal of Organic Chemistry

The Utilization of Organolithium Compounds for the Preparation of Tertiary Phosphines, Phosphine Oxides, and Phosphine Sulfides

C Screttas, AF Isbell

Index: Screttas,C.; Isbell,A.F. Journal of Organic Chemistry, 1962 , vol. 27, p. 2573 - 2577

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Citation Number: 30

Abstract

Six trialkyl-, triaryl-, or alkylarylphosphines have been prepared by condensing organolithium compounds with phosphorus trichloride or phenylphosphonous chloride. A number of methods have been investigated for the conversion of these phosphines into the corresponding oxides, sulfidea, and selenides. A convenient preparation of tertiary phosphine sulfides was developed. This involved the reaction of the mercuric chloride ...

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