Direct functionalization at the boron center of antiaromatic chloroborole

H Braunschweig, T Kupfer

Index: Braunschweig, Holger; Kupfer, Thomas Chemical Communications, 2008 , # 37 p. 4487 - 4489

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Citation Number: 35

Abstract

The presence of a reactive B–Cl bond allowed for the direct functionalization of the boron center in antiaromatic chloroborole ClBC4Ph4, thus allowing for a selective fine tuning of the optical properties of borole derivatives and facilitating a potential new approach toward the introduction of borole moieties into the backbone of organic π-conjugated frameworks.