Photochemical Rearrangement of 3, 3, 6-Trimethyl-1, 5-heptadien-4-one

OA Luzina, SM Adekenov, EM Suleimenov…

Index: Luzina; Adekenov; Suleimenov; Atazhanova; Salakhutdinov; Barkhash Russian Journal of Organic Chemistry, 2001 , vol. 37, # 5 p. 740 - 741

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Abstract

We previously examined photochemical reactions of some naturally occurring di-and trienones and their analogs, as well as the effect of complex formation with cyclodextrins on this process [1]. All these ketones had a common structural unit I (Scheme 1), and the main transformation was either carbocyclization (in the presence of cyclodextrin) or cis3trans isomerization (in the absence of cyclodextrin).

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