Organoboranes. 23. Reaction of organolithium and Grignard reagents with. alpha.-bromoalkylboronate esters. A convenient, essentially quantitative procedure for the …

HC Brown, NR De Lue, Y Yamamoto…

Index: Brown,H.C. et al. Journal of Organic Chemistry, 1977 , vol. 42, p. 4088 - 4092

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Citation Number: 38

Abstract

(1 1) Other conditions which gave some phosphonium salt, but were less successful, included carrying out the reaction without solvent, as well as in benzene, nitromethane, and dimethylformamide.(12) Utilization of pure THF for this reaction was unsatisfactory, ...

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Organoboranes. 32. Homologation of alkylboronic esters with methoxy (phenylthio) methyllithium: regio-and stereocontrolled aldehyde synthesis from olefins via …

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