Effects of metal ions on physicochemical properties and redox reactivity of phenolates and phenoxyl radicals: mechanistic insight into hydrogen atom abstraction by …

S Itoh, H Kumei, S Nagatomo, T Kitagawa…

Index: Itoh; Kumei; Nagatomo; Kitagawa; Fukuzumi Journal of the American Chemical Society, 2001 , vol. 123, # 10 p. 2165 - 2175

Full Text: HTML

Citation Number: 66

Abstract

Phenolate and phenoxyl radical complexes of a series of alkaline earth metal ions as well as monovalent cations such as Na+ and K+ have been prepared by using 2, 4-di-tert-butyl-6-(1, 4, 7, 10-tetraoxa-13-aza-cyclopentadec-13-ylmethyl) phenol (L1H) and 2, 4-di-tert-butyl-6-(1, 4, 7, 10, 13-pentaoxa-16-aza-cyclooctadec-16-ylmethyl) phenol (L2H) to examine the effects of the cations on the structure, physicochemical properties and redox reactivity of the ...

Related Articles:

Steric and Kinetic Isotope Effects in the Deprotonation of Cation Radicals of NADH Synthetic Analogs

[Anne, Agnes; Fraoua, Sylvie; Hapiot, Philippe; Moiroux, Jacques; Saveant, Jean-Michel Journal of the American Chemical Society, 1995 , vol. 117, # 28 p. 7412 - 7421]

Selective photoalkylation of 10-methylacridinium ion with tetra-alkylstannanes or diethylmercury using visible irradiation

[Fukuzumi, Shunichi; Kuroda, Sadaki; Tanaka, Toshio Journal of the Chemical Society, Chemical Communications, 1986 , # 20 p. 1553 - 1554]

Selective photoalkylation of 10-methylacridinium ion with tetra-alkylstannanes or diethylmercury using visible irradiation

[Fukuzumi, Shunichi; Kuroda, Sadaki; Tanaka, Toshio Journal of the Chemical Society, Chemical Communications, 1986 , # 20 p. 1553 - 1554]

Selective photoalkylation of 10-methylacridinium ion with tetra-alkylstannanes or diethylmercury using visible irradiation

[Fukuzumi, Shunichi; Kuroda, Sadaki; Tanaka, Toshio Journal of the Chemical Society, Chemical Communications, 1986 , # 20 p. 1553 - 1554]

More Articles...