Bicyclo [2.2. 2] octane-capped porphyrins. 1. Synthesis, characterization, and solution three-dimensional structure

HY Zhang, A Blasko, JQ Yu…

Index: Zhang, Hong-Yue; Blasko, Andrei; Yu, Jian-Qiu; Bruice, Thomas C. Journal of the American Chemical Society, 1992 , vol. 114, # 17 p. 6621 - 6630

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Citation Number: 28

Abstract

Abstract: Three novel capped porphyrins (bicyclo [2.2. 2] octane-capped porphyrins, VIAH2 and VIBH,, and bicyclo [2.2. 2]-oct-7-ene-capped porphyrin, VICH,) have been successfully synthesized by the Lewis acid (BF,. Et, O) catalyzed condensation of pyrrole with tetraacetals 6, 12, and 15, respectively. IH and I3C 1D and'H-IH 2D NMR (DQF-COSY and ROESY) of porphyrins WAH2 and VIBH2 and IH 1D and 2D NMR of VICH2 established that the ...

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