Dibenz [c, h] acridine receptors for dibutylmalonic acid. Decarboxylative catalytic activity

…, C Raposo, MF de la Torre, JR Morán, MC Caballero

Index: Mussons, Ma. Luisa; Raposo, Cesar; De la Torre, Ma. Fe; Moran, Joaquin R.; Caballero, Ma. Cruz Tetrahedron, 1999 , vol. 55, # 13 p. 4077 - 4094

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Citation Number: 7

Abstract

New molecular receptors with dibenz [c, h] acridine skeleton bearing functional groups complementary to malonic acids have been developed. Dibutylmalonic acid is bound in chloroform with Kass values between 102 and 105 M− 1 via hydrogen-bonding interactions. The catalytic ability of several of these receptors in the decarboxylative reaction of this diacid has been investigated.