1H fast MAS NMR studies of hydrogen-bonding interactions in self-assembled monolayers

…, M McCormick, S De Paul, R Graf, YS Lee…

Index: Pawsey, Shane; McCormick, Mark; De Paul, Susan; Graf, Robert; Lee; Reven, Linda; Spiess, Hans W. Journal of the American Chemical Society, 2003 , vol. 125, # 14 p. 4174 - 4184

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Citation Number: 129

Abstract

The structures formed by the adsorption of carboxyalkylphosphonic acids on metal oxides were investigated by 1H fast magic angle spinning (MAS), heteronuclear correlation (HETCOR), and 1H double-quantum (DQ) MAS solid-state NMR experiments. The diacids HO2C (CH2) n PO3H2 (n= 2, 3, 11, and 15) were adsorbed on TiO2 and two types of ZrO2 powders having average particle sizes of 20, 30, and 5 nm, respectively. ...