Alkylation and sulfenylation of amino thioethers. Tetrahydro-1, 3-thiazine and related compounds

JK Kim, Y Souma, N Beutow, C Ibbeson…

Index: Kim, Jhong K.; Souma, Yoshie; Beutow, Norman; Ibbeson, Chris; Caserio, Marjorie C. Journal of Organic Chemistry, 1989 , vol. 54, # 7 p. 1714 - 1720

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Citation Number: 18

Abstract

The reactants include N, N-dimethylmethanesulfenamide,[[(NJV-dimethy1amino) methyll thiolmethane, 1-(NJV-dimethylamino)-2-(methylthio) ethane, tetrahydro-1, 3-thiazine, tetrahydro-2-methyl-l, 3-thiazine, and the corresponding N-methyl and N-acetyl derivatives. Electrophiles include methyl iodide, ethyl iodide, 3-chloroand 3-bromopropene, trimethyloxonium fluoroborate, methanesdfenyl chloride, and dimethyl (methy1thio) ...

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