Addition de l'acétone à des alcynes vrais fonctionnels ou non

…, E Montaudon, R Lalande

Index: Gardrat, C.; Montaudon, E.; Lalande, R. Bulletin des Societes Chimiques Belges, 1980 , vol. 89, # 12 p. 1039 - 1042

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Abstract

Abstract Acetonyl radicals created by action of di-t-butylperoxide on acetone (molar ratios acetone/acetylenic compound/DTBP= 20/1/0.2; 150 C; 3h) add to acetylenic compounds and lead to the formation of 1/1 adducts in low to moderate yields. 2/1 adducts are not observed in these experimental conditions.

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