Tetrahedron letters

Catalyzed hydroboration of nitrostyrenes and 4-vinylaniline: a mild and selective route to aniline derivatives containing boronate esters

CM Vogels, A Decken, SA Westcott

Index: Vogels, Christopher M.; Decken, Andreas; Westcott, Stephen A. Tetrahedron Letters, 2006 , vol. 47, # 14 p. 2419 - 2422

Full Text: HTML

Citation Number: 13

Abstract

Transition metal catalyzed reactions of catecholborane (HBcat; cat= 1, 2-O2C6H4) with β- nitrostyrene and 3-nitrostyrene lead to products derived from competing hydrogenation and hydroboration of the alkene unit along with reduction of the nitro group. Hydroboration of 4- vinylaniline gave regioselective formation of either the branched or the linear organoboronate ester depending upon the catalyst precursors (ie, RhCl (PPh3) 3 or Rh ( ...

Related Articles:

Chemoselective Hydrogenation of the Olefinic Bonds Using a Palladium/Magnesium??Lanthanum Mixed Oxide Catalyst

[Kantam, Mannepalli Lakshmi; Kishore, Ramineni; Yadav, Jagjit; Sudhakar, Medak; Venugopal, Akula Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 663 - 669]

Selective hydrogenation of nitroarenes and olefins over rhodium nanoparticles on hydroxyapatite

[Huang, Lei; Luo, Pingfei; Pei, Weige; Liu, Xiaoyun; Wang, Yong; Wang, Jun; Xing, Weihong; Huang, Jun Advanced Synthesis and Catalysis, 2012 , vol. 354, # 14-15 p. 2689 - 2694]

Cecilia Torres, Cristian Campos, José Luis García Fierro, Marcelo Oportus &

[Campos, Cristian; Torres, Cecilia; Oportus, Marcelo; Pena, Miguel A.; Fierro; Reyes, Patricio Catalysis Today, 2013 , vol. 213, p. 93 - 100]

Synthesis of substituted 4-dimethylaminoazobenzenes and a study of their effect of Lactobacillus casei and Escherichia coli

[Bebawi,G.M.; Lambooy,J.P. Journal of Medicinal Chemistry, 1968 , vol. 11, p. 580 - 582]

Synthesis of substituted 4-dimethylaminoazobenzenes and a study of their effect of Lactobacillus casei and Escherichia coli

[Bebawi,G.M.; Lambooy,J.P. Journal of Medicinal Chemistry, 1968 , vol. 11, p. 580 - 582]

More Articles...