Chemistry of oxaziridines. 12. Oxidation of alkylidenetriphenylphosphoranes with N-sulfonyloxaziridines

FA Davis, BC Chen

Index: Davis, Franklin A.; Chen, Bang-chi Journal of Organic Chemistry, 1990 , vol. 55, # 1 p. 360 - 363

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Citation Number: 14

Abstract

N-Sulfonyloxaziridines, such as 3 and 4, developed in our laboratories, are useful aprotic oxidizing reagents for the hydroxylation of lithium and Grignard reagents to alcohols and phenolss and for the oxidation of enolates to a-hydroxy carbonyl compo~ nds.~ J~ Not only are these reagents readily prepared'J'and storable, but (camphorylsulfony1) oxaziridine (4) is now commercially available. 12 In connection with our interest in developing new ...