Synthesis of new pyrrole–pyridine-based ligands using an in situ Suzuki coupling method

M Böttger, B Wiegmann, S Schaumburg…

Index: Boettger, Matthias; Wiegmann, Bjoern; Schaumburg, Steffen; Jones, Peter G.; Kowalsky, Wolfgang; Johannes, Hans-Hermann Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 1037 - 1047

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Citation Number: 9

Abstract

Abstract The compounds 6-(pyrrol-2-yl)-2, 2 '-bipyridine, 2-(pyrrol-2-yl)-1, 10-phenanthroline and 2-(2-(N-methylbenz [d, e] imidazole)-6-(pyrrol-2-yl)-pyridine were synthesized by using an in situ generated boronic acid for the Suzuki coupling. Crystals of the products could be grown and exhibited interesting structures by X-ray analysis, one of them showing a chain- like network with the adjacent molecules linked to each other via intermolecular N–H… N ...