A new zinc difluorocarbenoid reagent

…, H Wojtowicz, CR Burkholder

Index: Dolbier, William R.; Wojtowicz, Hanna; Burkholder, Conrad R. Journal of Organic Chemistry, 1990 , vol. 55, # 19 p. 5420 - 5422

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Citation Number: 61

Abstract

Another indication of the normal behavior of our CF2: reagent was the fact that its reaction with norbornadiene led to a relative degree of 1, 4 versus 1, 2 carbene addition that was similar to that observed by Jefford in his study wherein the CF2 was derived from Burton's method6 (Le., decomposition of triphenyl (bromodifluoromethy1)-phosphonium bromide in triglyme). 16

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