Cycloalkano??2H??pyrrole als stabile Zwischenstufen bei der Umwandlung von β??Cycloalkenyl?螃窿?azidoacrylestern in Cycloalkano??1H??pyrrole

…, PG Jones, P Bubenitschek

Index: Vogel, Claus; Schnippenkoetter, Bernd; Jones, Peter G.; Bubenitschek, Peter Angewandte Chemie, 1993 , vol. 105, # 7 p. 1116 - 1117

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Abstract

Abstract Eine quantitative 1, 5-Elektrocyclisierung findet bei der Thermolyse der 2-Vinyl- cycloalkenyl-α-azidoacrylester 1 zu den substituierten Cycloalkano− 2H-pyrrolen 2 statt. Produkte aus der Reaktion des Vinylazids oder-nitrens mit der ungesättigten Seitenkette wurden nicht gefunden.

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