Acyl nitronates in organic synthesis. An expeditious synthesis of 2, 5-dialkylpyrrolidines and 2, 5-dialkylpyrrolines including ant venom alkaloids.
M Miyashita, BZE Awen, A Yoshikoshi
Index: Miyashita, Masaaki; Awen, Bahlul Z. E.; Yoshikoshi, Akira Chemistry Letters, 1990 , # 2 p. 239 - 242
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Citation Number: 14
Abstract
Acetyl nitronates (acetic nitronic anhydrides), readily obtainable from ketones and nitroalkenes, have been demonstrated to serve as potentially useful intermediates for the synthesis of 2, 5-dialkylpyrrolidines and 2, 5-dialkylpyrrolines, and a short-step synthesis of some ant venom alkaloids has been accomplished via these acetyl nitronates.
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