Journal of the American Chemical Society

Oxidation of organic compounds by zinc permanganate

S Wolfe, CF Ingold

Index: Wolfe, Saul; Ingold, Christopher F. Journal of the American Chemical Society, 1983 , vol. 105, # 26 p. 7755 - 7757

Full Text: HTML

Citation Number: 64

Abstract

Based on recovered THF, the conversion is MnO,'/g of reagent give essentially the same conversions. See text. Isolated yield. Reactions have not been optimized. Zn (MnO,),/SiO,. e Mg (MnO,),/SiO,. fKMnOJSi0,. g 94% of the starting material was recovered. 61%. No deprotection was observed with silica gel alone under these conditions. J The reaction proceeds via the sulfoxide, which can be detected by TLC after short reaction times.

Related Articles:

Phenylsilane as an active amidation reagent for the preparation of carboxamides and peptides

[Ruan, Zheming; Lawrence, R. Michael; Cooper, Christopher B. Tetrahedron Letters, 2006 , vol. 47, # 43 p. 7649 - 7651]

A reversible safety-catch method for the hydrogenolysis of N-benzyl moieties

[Johnson II, David C.; Widlanski, Theodore S. Tetrahedron Letters, 2004 , vol. 45, # 46 p. 8483 - 8487]

Synthesis and use of benzyl tert-butyl iminodicarbonate, a versatile reagent for the preparation of amines

[Grehn, Leif; Ragnarsson, Ulf Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 11B p. 2778 - 2786]

A reversible safety-catch method for the hydrogenolysis of N-benzyl moieties

[Johnson II, David C.; Widlanski, Theodore S. Tetrahedron Letters, 2004 , vol. 45, # 46 p. 8483 - 8487]

A reversible safety-catch method for the hydrogenolysis of N-benzyl moieties

[Johnson II, David C.; Widlanski, Theodore S. Tetrahedron Letters, 2004 , vol. 45, # 46 p. 8483 - 8487]

More Articles...