Synthese de trichloromethyl perfluoroalcanes [RF CCl 3, RF= C a F 2n+ 1 (n= 4, 6, 8)]

J Grondin, H Blancou, A Commeyras

Index: Grondin, J.; Blancou, H.; Commeyras, A. Journal of Fluorine Chemistry, 1989 , vol. 45, p. 349 - 354

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Citation Number: 5

Abstract

Abstract A new synthesis of trichloromethyl perfluoroalkanes (RF CCl 3) is described. This is accomplished by reaction of a perfluoroalkyl iodide (RFI) with carbon tetrachloride or bromotrichloromethane and zinc metal, in a chlorinated solvent; the influence of the solvent is discussed.