Tetrahedron

Reactivite de carbanions β cetophosphorothiolate: Réarrangement phosphorothiolate-phosphate d'énol

G Sturtz, M Baboulene

Index: Sturtz, G.; Baboulene, M. Tetrahedron, 1981 , vol. 37, # 17 p. 3067 - 3070

Full Text: HTML

Citation Number: 4

Abstract

The stabilization of S-alkanoate O, O-dialkyl phosphates carbanions has been tried. A enol phosphate-phosphorothiolate rearrangement is observed and the mechanism is described. This new transposition has been applied to the synthesis on various enol phosphates with thioether of enol function of phytosanitaire interest.