Inorganic chemistry

Tuning of Stepwise Neutral–Ionic Transitions by Acceptor Site Doping in Alternating Donor/Acceptor Chains

K Nakabayashi, M Nishio, H Miyasaka

Index: Aumueller, Alexander; Huenig, Siegfried Angewandte Chemie, 1984 , vol. 96, # 6 p. 437 - 438

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Abstract

... The first covalent DA system to undergo the N–I transition is the metal-complex chain compound [Ru 2 (2,3,5,6-F 4 PhCO 2 ) 4 DMDCNQI]·2(p-xylene) (0, 2,3,5,6-F 4 PhCO 2 – = 2,3,5,6-tetrafluorobenzoate, DMDCNQI = 2,5-dimethyl-N,N′-dicyanoquinonediimine, Scheme ...