Journal of Organometallic Chemistry

Photochemically generated silicon-carbon double-bonded intermidiates: II. Photolysis of aryldisilanes in the presence of dienes

M Ishikawa, T Fuchikami, M Kumada

Index: Ishikawa,M. et al. Journal of Organometallic Chemistry, 1976 , vol. 118, p. 139 - 153

Full Text: HTML

Citation Number: 0

Abstract

Abstract Photolysis of eight aryldisilanes in the presence of 1, 3-conjugated dienes (butadiene, isoprene and 2, 3-dimethylbutadiene) has been studied. All of the aryldisilanes bearing a hydrogen on an ortho carbon atom in the aryl ring reacted upon UV irradiation with the conjugated dienes to give o-silyl-substituted (3-butenylsilyl) arene derivatives in high yields. The 13 C and 1 H NMR, and mass spectroscopic studies of the products are ...

Related Articles:

Gold??Catalysed Oxyarylation of Styrenes and Mono??and gem??Disubstituted Olefins Facilitated by an Iodine (III) Oxidant

[Ball, Liam T.; Lloyd-Jones, Guy C.; Russell, Christopher A. Chemistry - A European Journal, 2012 , vol. 18, # 10 p. 2931 - 2937]

Studies on the synthesis and biological properties of non-carrier-added [125I and 131I]-labeled arylalkylidenebisphosphonates: potent bone-seekers for diagnosis …

[Arstad, Erik; Hoff, Per; Skattebol, Lars; Skretting, Arne; Breistol, Knut Journal of Medicinal Chemistry, 2003 , vol. 46, # 14 p. 3021 - 3032]

meta??Directing Cobalt??Catalyzed Diels–Alder Reactions

[Hilt, Gerhard; Janikowski, Judith; Hess, Wilfried Angewandte Chemie - International Edition, 2006 , vol. 45, # 31 p. 5204 - 5206]

Photolysis of organopolysilanes. Novel addition reaction of aryl substituted disilanes to olefins

[Ishikawa,M. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 5923 - 5924]

The electrochemical reductive trimethylsilylation of aryl chlorides: a good route to aryltrimethylsilanes and a novel route to tris (trimethylsilyl) cyclohexadienes

[Bordeau, Michel; Biran, Claude; Pons, Pierrette; Leger-Lambert, Marie-Pierre; Dunogues, Jacques Journal of Organic Chemistry, 1992 , vol. 57, # 17 p. 4705 - 4711]

More Articles...