Dimethylaminoboron dichloride and difluoride

JF Brown Jr

Index: Brown Journal of the American Chemical Society, 1952 , vol. 74, p. 1219

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Citation Number: 30

Abstract

The reaction of triethylamine with dimethylamine-boron trichloride in benzene solution gave a 73% yield of dimethylaminoboron dichloride. Pyridine with dimethylamine-boron trichloride gave mainly a 1: 1 adduct. There was no reaction between triethylamine and dimethylamine-boron trifluoride, but when dimethylamine-boron Muoride was pyrolyzed, it gave a 31% yield of dimethylaminoboron difluoride dimer, along with the ...