Thermal decompositions of N-nitrosohydroxylamines. II. N-acetyl-N-nitroso-O-tert-butylhydroxylamine

TW Koenig, M Deinzer

Index: Koenig,T.; Deinzer,M. Journal of the American Chemical Society, 1968 , vol. 90, p. 7014 - 7019

Full Text: HTML

Citation Number: 20

Abstract

Abstract: The decomposition of N-acetyl-N-nitroso-0-t-butylhydroxylamine has been studied under conditions of varying viscosity. The products include t-butyl peracetate and methyl t- butyl ether. The yields of these products increase with increasing viscosity. equilibration of the carbonyl oxygen label. The amount of cage combination from the deaminative radical pair is sig-nificantly lower than that which occurs from decomposition of the corresponding ...