Organic letters

Synthesis of Allylsilanes and Dienylsilanes by a One-Pot Catalytic C− H Borylation− Suzuki− Miyaura Coupling Sequence

VJ Olsson, KJ Szabo

Index: Olsson, Vilhelm J.; Szabo, Kalman J. Organic Letters, 2008 , vol. 10, # 14 p. 3129 - 3131

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Citation Number: 28

Abstract

Allylsilane and various vinyl substrates undergo selective C− H bond functionalization based boronation reactions using iridium catalysis. The products were further reacted with aryl and vinyl halogenides in a one-pot sequence. This method is suitable for regio-and stereoselective synthesis of various allylsilanes and dienylsilanes.

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