Journal of organometallic chemistry

Reversibility in free-radical reactions of aryltellurides with tributylstannyl, tributylgermyl and tris (trimethylsilyl) silyl radicals

CH Schiesser, MA Skidmore

Index: Schiesser, Carl H.; Skidmore, Melissa A. Journal of Organometallic Chemistry, 1998 , vol. 552, # 1-2 p. 145 - 157

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Citation Number: 26

Abstract

1H, 13C, 29Si, 77Se, 119Sn and 125Te NMR spectroscopies reveal that methyl, primary and secondary alkyl radicals, generated through the reaction of aryltelluroalkanes (4–9) with tributyltin hydride, tributylgermanium hydride or tris (trimethylsilyl) silane) under standard radical conditions (benzene, AIBN) are capable of displacing tributylstannyl, tributylgermyl and tris (trimethylsilyl) silyl radicals from aryltellurotributylstannanes (1, 2), ...

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