Double Carbonylation Reactions of Methyl-and Phenylpalladium (II) Complexes in the Presence of Secondary Amines Affording α-Keto Amides

F Ozawa, A Yamamoto

Index: Ozawa, Fumiyuki; Yamamoto, Akio Chemistry Letters, 1982 , p. 865 - 868

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Citation Number: 40

Abstract

The reactions of trans-PdR (X)(PMePh 2) 2 (R= Me, X= I and R= Ph, X= Br) with carbon monoxide in the presence of secondary amines, R'2 NH, were found to give α-keto amides, RCOCONR'2, as double carbonylation products under mild conditions in good yields and selectivities.