Tetrahedron

Synthesis and reactivity of iron carbonyl complexes of α, β-unsaturated acyl silanes

SE Thomas, GJ Tustin, A Ibbotson

Index: Thomas, Susan E.; Tustin, Gary J.; Ibbotson, Arthur Tetrahedron, 1992 , vol. 48, # 36 p. 7629 - 7640

Full Text: HTML

Citation Number: 14

Abstract

2-Trimethylsilyl-1-oxa-1, 3-butadiene (7) reacts with Fe2 (CO) 9 to form an unstable tetracarbonyliron (0) complex (8) whereas 2-trimethylsilyl-4-phenyl-1-oxa-1-oxa-1, 3- butadiene (9) and 2-(tert-butyldimethylsilyl)-4-phenyl-1-oxa-1, 3-butadiene (20) react with Fe2 (CO) 9 to form highly stable crystalline tricarbonyliron (0) complexes (16 and (21). Complexes (16) and (21) both undergo acylation when reacted with methyl lithium under ...

Related Articles:

Efficient synthesis of thioesters and amides from aldehydes by using an intermolecular radical reaction in water

[Nambu, Hisanori; Hata, Kayoko; Matsugi, Masato; Kita, Yasuyuki Chemistry - A European Journal, 2005 , vol. 11, # 2 p. 719 - 727]

Tetraethylammonium Bromide??Catalyzed Oxidative Thioesterification of Aldehydes and Alcohols

[Zhu, Xuebin; Shi, Yan; Mao, Haibin; Cheng, Yixiang; Zhu, Chengjian Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3558 - 3562]

A New and Efficient Esterification Reaction via Mixed Anhydrides by the Promotion of a Catalytic Amount of Lewis Acid.

[Miyashita, Mitsutomo; Shiina, Isamu; Miyoshi, So; Mukaiyama, Teruaki Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 5 p. 1516 - 1527]

Aromatic annulation with bisphenylthionium ions

[Manas, Abdul Rahman Bin; Smith, Robin A. J. Tetrahedron, 1987 , vol. 43, # 8 p. 1847 - 1856]

Aromatic annulation with bisphenylthionium ions

[Manas, Abdul Rahman Bin; Smith, Robin A. J. Tetrahedron, 1987 , vol. 43, # 8 p. 1847 - 1856]

More Articles...