A linear solvation energy relationship study for the reactivity of 2??(4??substituted phenyl)??cyclohex??1??enecarboxylic, 2??(4??substituted phenyl)??benzoic, and 2??(4?? …
JB Nikolić, GS Ušćumlić…
Index: Nikolc; Uscumlic; Juranic International Journal of Chemical Kinetics, 2010 , vol. 42, # 7 p. 430 - 439
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Abstract
Abstract The reactivities of 2-(4-substituted phenyl)-cyclohex-1-enecarboxylic acids, 2-(4- substituted phenyl)-benzoic acids, and 2-(4-substituted phenyl)-acrylic acids with diazodiphenylmethane in various solvents were investigated. To explain the kinetic results through solvent effects, the second-order rate constants of the examined acids were correlated using the Kamlet–Taft solvatochromic equation. The correlations of the kinetic ...
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