A facile conversion of aryl alkyl ketones into methyl 2-arylalkanoates using poly [4-(diacetoxyiodo) styrene]

SR Sheng, MH Zhong, XL Liu, QY Luo…

Index: Sheng, Shou-Ri; Zhong, Ming-Hua; Liu, Xiao-Ling; Luo, Qiu-Yan; Chen, Hui-Zong Journal of Chemical Research, 2004 , # 6 p. 392 - 393

Full Text: HTML

Citation Number: 0

Abstract

Treatment of aryl alkyl ketones with poly [4-(diacetoxyiodo) styrene] and trimethyl orthoformate in the presence of sulfuric acid followed by hydrolysis afforded methyl 2- arylalkanoates in good yields. The polymeric reagent can be regenerated and reused as an environmentally benign reagent.

Related Articles:

Palladium-catalyzed intermolecular α-arylation of zinc amide enolates under mild conditions

[Hama, Takuo; Liu, Xiaoxiang; Culkin, Darcy A.; Hartwig, John F. Journal of the American Chemical Society, 2003 , vol. 125, # 37 p. 11176 - 11177]

Highly Regioselective Anti-Markovnikov Palladium-Borate-Catalyzed Methoxycarbonylation Reactions: Unprecedented Results for Aryl Olefins

[Vieira, Tiago O.; Green, Mike J.; Alper, Howard Organic Letters, 2006 , vol. 8, # 26 p. 6143 - 6145]

Mechanistic Switch via Subtle Ligand Modulation: Palladium??Catalyzed Synthesis of α, β??Substituted Styrenes via C H Bond Functionalization

[Flores-Gaspar, Areli; Martin, Ruben Advanced Synthesis and Catalysis, 2011 , vol. 353, # 8 p. 1223 - 1228]

Mechanistic Switch via Subtle Ligand Modulation: Palladium??Catalyzed Synthesis of α, β??Substituted Styrenes via C H Bond Functionalization

[Flores-Gaspar, Areli; Martin, Ruben Advanced Synthesis and Catalysis, 2011 , vol. 353, # 8 p. 1223 - 1228]

Catalytic Methyl Transfer from Dimethylcarbonate to Carboxylic Acids

[Ji, Yuan; Sweeney, Jessica; Zoglio, Jillian; Gorin, David J. Journal of Organic Chemistry, 2013 , vol. 78, # 22 p. 11606 - 11611]

More Articles...