Russian journal of general chemistry

A Route to Organyl (trialkoxysilyl) chalcogenides and Dichalcogenides, Bis (trialkoxysilylmethyl) chalcogenides and Dichalcogenides

MS Sorokin, MG Voronkov

Index: Sorokin, M. S.; Voronkov, M. G. Russian Journal of General Chemistry, 2001 , vol. 71, # 12 p. 1883 - 1890 Zhurnal Obshchei Khimii, 2001 , vol. 71, # 12 p. 1988 - 1995

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Citation Number: 5

Abstract

Abstract Reactions of organylchalcogenomagnesium halides RYMgX (in situ)(R= Me, Et, Ph; Y= S, Se, Te; X= Br, I) with (halomethyl) trialkoxysilanes X'CH 2 Si (OR') 3 (X'= Cl, I; R'= Me, Et) at reflux in tetrahydrofuran and the systems of tetrahydrofuran-acetonitrile 1: 2, and ether- acetonitrile 1: 2 are studied. These reactions are shown to lead to formation of mixtures of corresponding organyl (trialkoxysilylmethyl) chalcogenide and-dichalcogenide, bis ( ...

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