Organic letters

Catalytic hydrophosphination of styrenes

MO Shulyupin, MA Kazankova, IP Beletskaya

Index: Shulyupin, Mstislav O.; Kazankova, Marina A.; Beletskaya, Irina P. Organic Letters, 2002 , vol. 4, # 5 p. 761 - 763

Full Text: HTML

Citation Number: 128

Abstract

The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in benzene under Ni [P (OEt) 3] 4 catalysis proceeds with high yield and selectivity to give only anti-Markovnikov product.

Related Articles:

Fluoride-mediated phosphination of alkenes and alkynes by silylphosphines

[Hayashi, Minoru; Matsuura, Yutaka; Watanabe, Yutaka Tetrahedron Letters, 2004 , vol. 45, # 50 p. 9167 - 9169]

Complexes acetyleniques de titane (II). Reactivite vis-a-vis de l'hydrogene moleculaire: Une nouvelle approche du titanocene

[Demerseman, Bernard; Coupanec, Pascale Le; Dixneuf, Pierre H. Journal of Organometallic Chemistry, 1985 , vol. 287, p. C35 - C38]

Reactions of lithiated P-diphenyl (alkyl)(N-methoxycarbonyl) phosphazenes with Michael acceptors and aldehydes. Synthesis of 1H-1, 2-azaphosphinin-6-ones, β- …

[Alvarez-Gutierrez, Julia M; Peralta-Perez, Emma; Perez-Alvarez, Isidro; Lopez-Ortiz, Fernando Tetrahedron, 2001 , vol. 57, # 15 p. 3075 - 3086]

Synthesis of 1, 2-dihydro-1, 3-diaza-2λ 5, 4λ 5-2, 4-diphosphorine 2-oxides

[Andujar, Carmen M; Alvarez, Isidro Perez; Ortiz, Fernando Lopez Tetrahedron, 2002 , vol. 58, # 13 p. 2569 - 2575]

Alkali??Phosphorverbindungen und ihr reaktives Verhalten, XLVI. Zur Umsetzung der Alkaliphosphide MePR2 mit ungesättigten Kohlenwasserstoffen

[Issleib,K.; Jasche,K. Chemische Berichte, 1967 , vol. 100, p. 412 - 420]

More Articles...