Tetrahedron letters

Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions

NT Patil, Y Yamamoto

Index: Patil, Nitin T.; Yamamoto, Yoshinori Tetrahedron Letters, 2004 , vol. 45, # 15 p. 3101 - 3103

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Citation Number: 37

Abstract

The reaction of allylic alcohols with carbon pronucleophiles in the presence of the Pd (PPh3) 4/carboxylic acid combined catalytic system, under neat conditions (without an organic solvent or without water as the solvent) enabled the direct allylation of the pronucleophiles, giving the corresponding allylated products in high yields.

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