Relation between the N-NO2 bond length and stability of the secondary nitramines

GM Nazin, VG Prokudin, VV Dubikhin, ZG Aliev…

Index: Nazin; Prokudin; Dubikhin; Aliev; Zbarskii; Yudin; Shastin Russian Journal of General Chemistry, 2013 , vol. 83, # 6 p. 1071 - 1076 Zh. Obshch. Khim., 2013 , vol. 83, # 6 p. 1071 - 1076,6

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Citation Number: 2

Abstract

Abstract The fact of the constancy of activation entropy of N-NO 2 bond homolysis in a series of secondary nitramines was utilized for correction of the experimental values of activation energy E of this process proceeding from the reliable data for the rate constants of the nitramines decomposition in solutions. When comparing the refined values of E (kJ mol− 1) with the NN bond length d NN (Å) the following correlations were obtained: for cyclic and ...