Crystal structure, configurational and density functional theory analysis of nickel (II) complexes with pentadentate 1, 3-pd3a-type ligands

…, M Djukić, M Vasojević, A Meetsma, ZD Matović

Index: Belosevic, Svetlana; Cendic, Marina; Djukic, Maja; Vasojevic, Miorad; Meetsma, Auke; Matovic, Zoran D. Inorganica Chimica Acta, 2013 , vol. 399, p. 146 - 153

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Abstract

The O–O–N–N–O-type pentadentate ligands H31, 3-pd3a and H31, 3-pd2ap (H31, 3-pd3a stands for 1, 3-propanediamine-N, N, N′-triacetic acid; H31, 3-pd2ap stands for 1, 3- propanediamine-N, N′-diacetic-N-3-propionic acid) and the corresponding novel octahedral nickel (II) complexes have been prepared and characterized. H31, 3-pd3a and H31, 3-pd2ap ligands coordinate to nickel (II) ion via five donor atoms (three deprotonated ...