ortho-Lithiations Reassessed: the Advantages of Deficiency Catalysis in Hydrocarbon Media

…, MG Slocum, RD Sandlin, EG Holland, D Kusmic…

Index: Slocum; Reinscheld, Thomas K.; White, Christopher B.; Timmons, Michael D.; Shelton, Philip A.; Slocum, Matthew G.; Sandlin, Rebecca D.; Holland, Erica G.; Kusmic, Damir; Jennings, John A.; Tekin, Kristen C.; Nguyen, Quang; Bush, Steven J.; Keller, Julia M.; Whitley, Paul E. Organometallics, 2013 , vol. 32, # 6 p. 1674 - 1686

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Citation Number: 8

Abstract

Hydrocarbon media based metalation procedures involving “deficiency catalysis” are described for the ortho-lithiation of anisole (A), p-chloroanisole (p-ClA), o-, m-, p- methylanisoles (o-, m-, p-MA), the three dimethoxybenzenes (DMB's), dimethylaniline (DMA), dimethybenzylamine (DMBA), m-methoxydimethylaniline (m-MeODMA), and tetramethyl-p-phenylenediamine (p-TMPDA). These procedures involve certain ...