Synthetic Communications

α-Isothiocyanatoacrylic esters

RA Volkmann

Index: Volkmann,R.A. Synthetic Communications, 1978 , vol. 8, p. 541 - 547

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Citation Number: 3

Abstract

Abstract Although allylic thiocyanates undergo a facile thermal (3, 3) isomerization to form the more stable allylic isothiocyanates1, this transformation has played a surprisingly minor role in organic synthesis. We have found that α, β-unsaturated esters (1) can be converted to α-isothiocyanatoacrylic esters (2) via an allylic (3, 3) thiocyanate isomerization.

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