Silver-Catalyzed Highly Regioselective Synthesis of α-Carbonyl Furans from Enynones

ZW Chen, MT Luo, DN Ye, ZG Zhou, M Ye…

Index: Chen, Zheng-Wang; Luo, Miao-Ting; Ye, Dong-Nai; Zhou, Zhong-Gao; Ye, Min; Liu, Liang-Xian Synthetic Communications, 2014 , vol. 44, # 12 p. 1825 - 1831

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Abstract

The fluorous biphase system (FBS), first reported by Horváth and Rábai in 1994, [ 12 12. Horváth , IT ; Rábai , J. Science 1994 , 266 , 72 . [CrossRef], [PubMed], [Web of Science ®] View all references ] has attracted considerable interest. It bears some potential advantages over classical homogenous systems, including easy separation and recycling of the catalyst. Moreover, the perfluorinated hydrocarbons are ideal solvents for organic transformation; for example, they have ...

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