The Journal of organic chemistry

Synthesis of a C29-C51 Subunit of Spongistatin 1 (Altohyrtin A) Starting from (R)-3-Benzyloxy-2-methylpropan-1-ol

S Lemaire-Audoire, P Vogel

Index: Dahmann, Georg; Hoffmann, Reinhard W. Liebigs Annalen der Chemie, 1994 , # 8 p. 837 - 846

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Citation Number: 30

Abstract

... with (tert-butyl)dimethylsilyl 4-deoxy-2,3-di-O-(methoxymethyl)-4-methyl-6-O-(tert-butyl) dimethylsilyl)-β-d-glycero-l-gluco-heptodialdo-1,5-pyranoside ((+)-7) and a C-glycosidation of (4R,7R&S,E)-7,8-dichloro-2-methylidene-1-(trimethylsilyl)oct-5-en-4-yl p-methoxybenzoate (16). ...