An efficient electrochemical synthesis of diamino-o-benzoquinone: Mechanistic and kinetic evaluation of the reaction of azide ion with o-benzoquinone

…, T Shariatmanesh, M Hesari, M Shojaeifard

Index: Nematollahi, Davood; Afkhami, Abbas; Tammari, Esmail; Shariatmanesh, Tahere; Hesari, Mahdi; Shojaeifard, Maryam Chemical Communications, 2007 , # 2 p. 162 - 164

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Citation Number: 27

Abstract

An efficient method for the synthesis of diamino-o-benzoquinone based on the Michael reaction of electrochemically generated o-benzoquinone with azide ion is described, as well as an estimation of the homogeneous rate constant (kobs) of the reaction of o-benzoquinone with azide ion by the digital-simulation method.