Chemistry by Nanocatalysis: First Example of a Solid??Supported RAPTA Complex for Organic Reactions in Aqueous Medium

SE García??Garrido, J Francos, V Cadierno…

Index: Garcia-Garrido, Sergio E.; Francos, Javier; Cadierno, Victorio; Basset, Jean-Marie; Polshettiwar, Vivek ChemSusChem, 2011 , vol. 4, # 1 p. 104 - 111

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Citation Number: 78

Abstract

Abstract A ruthenium–arene–PTA (RAPTA) complex has been supported for the first time on an inorganic solid, that is, silica-coated ferrite nanoparticles. The resulting magnetic material proved to be a general, very efficient and easily reusable catalyst for three synthetically useful organic transformations; selective nitrile hydration, redox isomerization of allylic alcohols, and heteroannulation of (Z)-enynols. The use of low metal concentration, ...

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