Syntheses, structure, reactivity and species recognition studies of oxo-vanadium (V) and-molybdenum (VI) complexes†

…, MB Verghese, K Rissanen, E Kolehmainen…

Index: Rao, Chebrolu P.; Sreedhara, Alavattam; Rao, P. Venkateswara; Verghese, M. Bindu; Rissanen, Kari; Kolehmainen, Erkki; Lokanath; Sridhar; Prasad, J. Sashidhara Journal of the Chemical Society - Dalton Transactions, 1998 , # 14 p. 2383 - 2393

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Citation Number: 49

Abstract

Alkoxo-rich Schiff-bases of potentially tri-, tetra-and penta-dentate binding capacity, and their sodium tetrahydroborate-reduced derivatives, have been synthesized. Their oxo-vanadium (V) and-molybdenum (VI) complexes were synthesized and characterized using several analytical and spectral techniques including multinuclear NMR spectroscopy and single- crystal X-ray diffraction studies. Eight structurally different types of complexes possessing ...