Group IVb metalloidal and mercury substituent effects in the naphthalene system by fluorine-19 nuclear magnetic resonance

W Adcock, SQA Rizvi, W Kitching…

Index: Adcock,W. et al. Journal of the American Chemical Society, 1972 , vol. 94, p. 369 - 374

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Citation Number: 14

Abstract

Abstract: A number of substituted a (1)-and/?(2)-fluoronaphthalenes with metallo substituents of the type MR,(when M is a group IVb metalloid; R= methyl) and HgX (X= halogen or aryl) in the 4, 6, and 7 positions have been synthesized and their fluorine nmr spectra have been measured. The'9F substituent chemical shift data (the extent to which a substituent electronically perturbs the CF neighborhood is indicated by the substituent ...