Russian journal of organic chemistry

Reactions of 3-azido-1, 2, 4-triazole with electrophiles

TP Kofman, KN Krasnov

Index: Kofman; Krasnov Russian Journal of Organic Chemistry, 2004 , vol. 40, # 11 p. 1651 - 1656

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Citation Number: 16

Abstract

Abstract Alkylation of 3-azido-1, 2, 4-triazole with oxiranes, bromoacetone, and methyl vinyl ketone furnished a mixture of N-substituted 3-and 5-azido-1, 2, 4-triazoles, 3-azido compounds prevailing. The same substrate subjected to heterylation with 3, 5-dinitro-1, 2, 4- triazole derivatives reacted selectively at the N 1 atom, and its bromination afforded 3-azido- 5-bromo-1, 2, 4-triazole..